Where the goods are found to be in retail packaging, you should always take whole retail packages as your sample. You may take more than one package if this is necessary to reach the minimum sample size.

Where the goods are found to be articles (e.g. timber, metal castings or sheets) you should generally take whole items.

However, for goods that are in bulk or in wholesale packages you will usually need to take smaller samples. It is important that you use the correct type of storage container for the goods.


1. Sample containers: general information and requirements

The type of container you should use for storing and transporting the samples is determined by the physical and chemical properties of the goods and the storage and transport requirements.

The container used for packing samples taken must meet the following requirements:

In choosing sampling containers you must follow the principles listed in Table 1.

The stoppers and caps used for closing the sample holders (bottles/containers) must ensure a tight seal to prevent any leakage or evaporation of the samples. The material of which the containers and stoppers are made must not be susceptible to chemical attack by the samples and must not interact with or contaminate them.

Depending on the nature of samples taken crown caps, plastic or metal screw caps additionally reinforced to ensure better sealing can be used. The use of cork and rubber plugs should be avoided.

The most commonly used sample containers are plastic or metal containers, glass bottles, metal canisters and plastic bags or boxes (see Table 2). The design of sample containers may vary in different Member States. The list of sample containers is therefore not exhaustive and other types of packages may be used provided they meet all the requirements.

Table 1
Type of goods Requirements for the package
Goods to be examined for humidity and fat content Packaging must not absorb moisture or fat.
Perishable, frozen, and cooled goods Packaging must not be affected by low temperature.
Goods containing volatile components Stopper or cap must allow air-tight closure.
Liquid goods, prone to fermentation Packaging must be closed with a screw-type stopper or cap.

Samples of fruit juices or juices of plant origin must be frozen immediately and kept frozen until analysed.

All other fermentable liquids must be mixed with 2 g of salicylic acid per 1 litre of sample, or another fermentation-slowing agent at an appropriate concentration.


Table 2
No Type of Goods Packaging Recommendation
1 Petroleum Products - liquid fuels, lubricants Metal containers
Glass bottles
Polypropylene (PP) bottles
Polyethylenterephtalate (PET) bottles
2 Organic solvents Metal containers
Glass bottles
Polypropylene (PP) bottles
Polyethylenterephtalate (PET) bottles
3 Liquid vegetable oils and fats Metal containers
Glass bottles
Glass jars
Polypropylene (PP) bottles
Polyethylenterephtalate (PET) bottles
4 Various types of chemical substances Metal containers
Glass bottles
Polypropylene (PP) bottles
Polyethylenterephtalate (PET) bottles
5 Food products Paper bags
Polyethylene (PE) and polypropylene (PP) bags, bottles, etc.
Glass jars
6 Spirits and ethyl alcohol Glass bottles
Polypropylene (PP) bottles
Polyethylenterephtalate (PET) bottles



2. List of Sample Containers

Code Container Type Suitable for
P00 Plastic bags
Different sizes
With or without pre-printed label

Click to enlarge picture
  • Goods taken in form of pieces such as tiles, wood, paper, textiles, metal sheets, various articles, etc.
  • goods in their retails sale packages
  • tobacco
  • dried fruit
  • flour
  • sand
  • sugar
  • starch
P01 Plastic bottle
Narrow opening
Normal size
100 ml to 500 ml
Leak-proof closure

Click to enlarge picture
Non-volatile liquids, such as:
  • petroleum products such as kerosene, gas oil, heating oil, lubricants etc. with exception of gasoline
  • fatty acids methylesters (FAME) and mixtures of FAME with mineral oils
  • vegetable oils
  • juices and syrups
  • non-alcoholic beverages
  • surface active agents and preparations
  • non-volatile chemicals and chemical preparation
P02 Plastic bottle
Narrow opening
Normal size
50 ml to 100 ml
Leak-proof closure

Click to enlarge picture
High-value goods, such as:
  • fragment of precious metals
  • diamonds
  • pure chemicals
  • spices
  • metal chips or fragments
P03 Plastic bottle
Wide mouth opening
Normal size
100 ml to 500 ml
Leak-proof closure

Click to enlarge picture
Powdered and granulated materials or pastes, such as:
  • lubricating greases
  • Vaseline
  • sand
  • sugar
  • starch
  • instant beverages
  • tea
  • solidified vegetable oils and fats
  • tobacco
P04 Plastic bottle
Wide mouth opening
Normal size
500 ml to 1000 ml
Leak-proof closure

Click to enlarge picture
Dried fruit, powdered materials and pastes, such as:
  • flour
  • paints and varnishes
P05 Plastic bottle
Small size
50 ml to 100 ml
Air-tight closure

Click to enlarge picture
High-value volatile liquids, such as:
  • foodstuffs aromatics
  • foodstuff supplements
  • fragrances, cosmetics, essences etc.
  • light-sensitive materials (stored in dark containers)
P06 Plastic bottle
Small size
100 ml to 500 ml
Air-tight closure

Click to enlarge picture
Liquids, such as:
  • spirit and alcoholic beverages
  • denatured spirit
  • antifreeze solutions
  • soap and cleaning solutions
  • organic solvents and thinners
P07 Plastic bottle
Normal size
500 ml to 1000 ml
Air-tight closure

Click to enlarge picture
Liquid foodstuffs, such as:
  • wine
  • beer
  • low-alcohol beverages and solutions
R00 Paper bags
Different sizes
With or without pre-printed label

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  • Tobacco
  • Plants
  • Goods taken in form of pieces, such as: tiles, wood, paper, textiles, metal sheets and articles.
R01 Cardboard boxes, cartons
Different sizes
With or without pre-printed label

Click to enlarge picture
  • Tobacco
  • Plants
  • Goods taken in form of pieces, such as: tiles, wood, paper, textiles, metal sheets and articles.
G01 Glass bottle
Large size
500 ml to 1000 ml
Leak-proof closure

Click to enlarge picture
Special liquids, such as:
  • white spirit
  • gasoline
  • spirit and alcoholic beverages
  • light sensitive samples (e.g. olive oil)
  • organic solvents and thinners
  • light sensitive liquids (stored in dark receptacles)
M01 Metal can
Large size
500 ml to 1000 ml
Leak-proof closure

Click to enlarge picture
Special liquids, such as:
  • white spirit
  • gasoline
  • spirit and alcoholic beverages
  • organic solvents and thinners
  • light sensitive liquids (e.g vegetable oils)
M02 Metal bottle
Large size
500 ml to 1000 ml
Narrow opening
Leak-proof closure

Click to enlarge picture
Special liquids, such as:
  • white spirit
  • gasoline
  • spirit and alcoholic beverages
  • organic solvents and thinners
Do not use for acidic or basic liquids, such as vinegar or brine!
M10 Metal gas cylinder
Medium size

Click to enlarge picture
Gases and liquefied gases



Revisions
Version Date Changes
1.0 12.10.2012 First version
1.1 15.07.2018 Update – added: R00, R01, M02 and M10
1.2 10.02.2021 Update – corrections for P06 and G01