European Commission - Growth

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EC Regulation (v.2)

Annex IV

LIST OF COLORANTS ALLOWED IN COSMETIC PRODUCTS

Ref. Substance identification Conditions
Chemical name Colour index Number / Name of Common Ingredients Glossary CAS Number EC Number Colour Product Type, body parts Maximum concentration in ready for use preparation
1 Sodium tris(1,2-naphthoquinone 1-oximato-O,O')ferrate(1-) CI 10006     Green  Rinse-off product   
2 Trisodium tris[5,6-dihydro-5-(hydroxyimino)-6-oxonaphthalene-2-sulphonato(2-)-N5,O6]ferrate(3-) CI 10020     Green  Not to be used in products applied on mucous membranes   
3 Disodium 5,7-dinitro-8-oxidonaphthalene-2-sulphonate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 10316     Yellow  Not to be used in eye products   
4 2-[(4-Methyl-2-nitrophenyl)azo]-3-oxo-N-phenylbutyramide CI 11680     Yellow  Not to be used in products applied on mucous membranes   
5 2-[(4-Chloro-2-nitrophenyl)azo]-N-(2-chlorophenyl)-3-oxobutyramide CI 11710     Yellow  Not to be used in products applied on mucous membranes   
6 2-[(4-Methoxy-2-nitrophenyl)azo]-3-oxo-N-(o-tolyl)butyramide CI 11725     Orange  Rinse-off products   
7 4-(Phenylazo)resorcinol CI 11920     Orange     
8 4-[(4-Ethoxyphenyl)azo]naphthol CI 12010     Red  Not to be used in products applied on mucous membranes   
9 1-[(2-Chloro-4-nitrophenyl)azo]-2-naphthol and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 12085     Red    3% 
10 1-[(4-Methyl-2-nitrophenyl)azo]-2-naphthol CI 12120     Red  Rinse-off products   
11 3-Hydroxy-N-(o-tolyl)-4-[(2,4,5-trichlorophenyl)azo]naphthalene-2-carboxamide CI 12370     Red  Rinse-off products   
12 N-(4-Chloro-2-methylphenyl)-4-[(4-chloro-2-methylphenyl)azo]-3-hydroxynaphthalene-2-carboxamide CI 12420     Red  Rinse-off products   
13 4-[(2,5-Dichlorophenyl)azo]-N-(2,5-dimethoxyphenyl)-3-hydroxynaphthalene-2-carboxamide CI 12480     Brown  Rinse-off products   
14 N-(5-Chloro-2,4-dimethoxyphenyl)-4-[[5-[(diethylamino)sulphonyl]-2-methoxyphenyl]azo]-3-hydroxynaphthalene-2-carboxamide CI 12490     Red     
15 2,4-Dihydro-5-methyl-2-phenyl-4-(phenylazo)-3H-pyrazol-3-one CI 12700     Yellow  Rinse-off products   
16 Disodium 2-amino-5-[(4-sulphonatophenyl)azo]benzenesulphonate CI 13015     Yellow     
17 Sodium 4-(2,4-dihydroxyphenylazo)benzenesulphonate CI 14270     Orange     
18 Disodium 3-[(2,4-dimethyl-5-sulphonatophenyl)azo]-4-hydroxynaphthalene-1-sulphonate CI 14700     Red     
19 Disodium 4-hydroxy-3-[(4-sulphonatonaphthyl)azo]naphthalenesulphonate CI 14720   222-657-4  Red     
20 Disodium 6-[(2,4-dimethyl-6-sulphonatophenyl)azo]-5-hydroxynaphthalene-1-sulphonate CI 14815     Red     
21 Sodium 4-[(2-hydroxy-1-naphthyl)azo]benzenesulphonate and its unsoluble barium, strontium and zirconium lakes, salts and pigments CI 15510     Orange  Not to be used in eye products   
22 Calcium disodium bis[2-chloro-5-[(2-hydroxy-1-naphthyl)azo]-4-sulphonatobenzoate] CI 15525     Red     
23 Barium bis[4-[(2-hydroxy-1-naphthyl)azo]-2-methylbenzenesulphonate] CI 15580     Red     
24 Sodium 4-[(2-Hydroxy-1-naphthyl)azo]naphthalenesulphonate CI 15620     Red  Rinse-off products   
25 Sodium 2-[(2-hydroxynaphthyl)azo]naphthalenesulphonate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 15630     Red    3%  
26 Calcium bis[3-hydroxy-4-(phenylazo)-2-naphthoate] CI 15800     Red  Not to be used in products applied on mucous membranes    
27 Disodium 3-hydroxy-4-[(4-methyl-2-sulphonatophenyl)azo]-2-naphthoate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 15850   226-109-5  Red     
28 Disodium 4-[(5-chloro-4-methyl-2-sulphonatophenyl)azo]-3-hydroxy-2-naphthoate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 15865     Red     
29 Calcium 3-hydroxy-4-[(1-sulphonato-2-naphthyl)azo]-2-naphthoate CI 15880     Red     
30 Disodium 6-hydroxy-5-[(3-sulphonatophenyl)azo]naphthalene-2-sulphonate CI 15980     Orange     
31 Disodium 6-hydroxy-5-[(4-sulphonatophenyl)azo]naphthalene-2-sulphonate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 15985   220-491-7  Yellow     
32 Disodium 6-hydroxy-5-[(2-methoxy-4-sulphonato-m-tolyl)azo]naphthalene-2-sulphonate CI 16035   247-368-0  Red     
33 Trisodium 3-hydroxy-4-(4'-sulphonatonaphthylazo)naphthalene-2,7-disulphonate CI 16185   213-022-2  Red     
34 Disodium 7-hydroxy-8-(phenylazo)naphthalene-1,3-disulphonate CI 16230     Orange  Not to be used in products applied on mucous membranes   
35 Trisodium 1-(1-naphthylazo)-2-hydroxynaphthalene-4',6,8-trisulphonate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 16255   220-036-2  Red     
36 Tetrasodium 7-hydroxy-8-[(4-sulphonato-1-naphthyl)azo]naphthalene-1,3,6-trisulphonate CI 16290     Red     
37 Disodium 5-amino-4-hydroxy-3-(phenylazo)naphthalene-2,7-disulphonate and its unsoluble barium, strontium and zirconium lakes, salts and pigments CI 17200     Red     
38 Disodium 5-acetylamino-4-hydroxy-3-(phenylazo)naphthalene-2,7-disulphonate CI 18050   223-098-9  Red  Not to be used in products applied on mucous membranes   
39 2,7-Naphthalenedisulfonic acid, 3-((4-cyclohexyl-2-methylphenyl)azo)-4-hydroxy-5-(((4-methylphenyl)sulfonyl)amino)-, disodium salt CI 18130     Red  Rinse-off products   
40 Hydrogen bis[2-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]benzoato(2-)]chromate(1-) CI 18690     Yellow  Rinse-off products   
41 Disodium hydrogen bis[5-chloro-3-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-2-hydroxybenzenesulphonato(3-)]chromate(3-) CI 18736     Red  Rinse-off products   
42 Sodium 4-(3-hydroxy-5-methyl-4-phenylazopyrazol-2-yl)benzenesulphonate CI 18820     Yellow  Rinse-off products   
43 Disodium 2,5-dichloro-4-(5-hydroxy-3-methyl-4-((sulphophenyl)azo)pyrazol-1-yl)benzenesulphonate CI 18965     Yellow     
44 Trisodium 5-hydroxy-1-(4-sulphophenyl)-4-((4-sulphophenyl)azo)pyrazole-3-carboxylate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 19140   217-699-5   Yellow     
45 N,N'-(3,3'-Dimethyl[1,1'-biphenyl]-4,4'-diyl)bis[2-[(2,4-dichlorophenyl)azo]-3-oxobutyramide] CI 20040     Yellow  Rinse-off products   
46 Sodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)azo]-6-(phenylazo)naphthalene-2,7-disulphonate CI 20470     Black  Rinse-off products   
47 2,2'-[(3,3'-Dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2,4-dimethylphenyl)-3-oxobutyramide] CI 21100     Yellow  Rinse-off products   
48 2,2'-[(3,3'-Dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(4-chloro-2,5-dimethoxyphenyl)-3-oxobutyramide] CI 21108     Yellow  Rinse-off products   
49 2,2'-[Cyclohexylidenebis[(2-methyl-4,1-phenylene)azo]]bis[4-cyclohexylphenol] CI 21230     Yellow  Not to be used in products applied on mucous membranes   
50 Disodium 4,6-dihydroxy-3-[[4-[1-[4-[[1-hydroxy-7-[(phenylsulphonyl)oxy]-3-sulphonato-2-naphthyl]azo]phenyl]cyclohexyl]phenyl]azo]naphthalene-2-sulphonate CI 24790     Red  Rinse-off products   
51 1-(4-(Phenylazo)phenylazo)-2-naphthol CI 26100     Red  Not to be used in products applied on mucous membranes   
52 Tetrasodium 6-amino-4-hydroxy-3-[[7-sulphonato-4-[(4-sulphonatophenyl)azo]-1-naphthyl]azo]naphthalene-2,7-disulphonate CI 27755     Black     
53 Tetrasodium 1-acetamido-2-hydroxy-3-(4-((4-sulphonatophenylazo)-7-sulphonato-1-naphthylazo))naphthalene-4,6-disulphonate CI 28440   219-746-5  Black     
54 Benzenesulfonic acid, 2,2'-(1,2-ethenediyl)bis-5-nitro-, disodium salt, reaction products with 4-[(4-aminophenyl)azo]benzenesulfonic acid, sodium salts CI 40215     Orange  Rinse-off products   
55 beta Carotene CI 40800   230-636-6   Orange     
56 8'-apo-.beta.-Caroten-8'-al CI 40820     Orange     
57 Ethyl 8'-apo-.beta.-caroten-8'-oate CI 40825   214-173-7  Orange     
58 Canthaxanthin CI 40850   208-187-2  Orange     
59 Ammonium, (4-(alpha-(p-(diethylamino)phenyl)-2,4-disulfobenzylidene)-2,5-cyclohexadien-1-ylidene)diethyl-, hydroxide, monosodium salt CI 42045     Blue  Not to be used in products applied on mucous membranes   
60 Ethanaminium, N-(4-((4-(diethylamino)phenyl)(5-hydroxy-2,4-disulfophenyl)methylene)-2,5-cyclohexadien-1-ylidene)-N-ethylhydroxide, inner salt, calcium salt (2:1) and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 42051   222-573-8  Blue     
61 Benzene-methanaminium, N-ethyl-N-(4-((4-(ethyl((3-sulfophenyl)methyl)amino)phenyl)(4-hydroxy-2-sulfophenyl)methylene)-2,5-cyclohexadien-1-ylidene)-3-sulfo-, hydroxide, inner salt, disodium salt CI 42053     Green     
62 Hydrogen (benzyl)[4-[[4-[benzylethylamino]phenyl](2,4-disulphonatophenyl)methylene]cyclohexa-2,5-dien-1-ylidene](ethyl)ammonium, sodium salt CI 42080     Blue  Rinse-off products   
63 Benzenemethanaminium, N-ethyl-N-(4-((4-(ethyl((3-sulfophenyl)methyl)amino)phenyl)(2-sulfophenyl)methylene)-2,5-cyclohexadien-1-ylidene)-3-sulfo-, hydroxide, inner salt, disodium salt CI 42090   223-339-8   Blue     
64 Hydrogen [4-[(2-chlorophenyl)[4-[ethyl(3-sulphonatobenzyl)amino]phenyl]methylene]cyclohexa-2,5-dien-1-ylidene](ethyl)(3-sulphonatobenzyl)ammonium, sodium salt CI 42100     Green  Rinse-off products   
65 Hydrogen [4-[(2-chlorophenyl)[4-[ethyl(3-sulphonatobenzyl)amino]-o-tolyl]methylene]-3-methylcyclohexa-2,5-dien-1-ylidene](ethyl)(3-sulphonatobenzyl)ammonium, sodium salt CI 42170     Green  Rinse-off products   
66 (4-(4-Aminophenyl)(4-iminocyclohexa-2,5-dienylidene)methyl)-2-methylaniline hydrochloride CI 42510     Violet  Not to be used in products applied on mucous membranes   
67 4-[(4-Amino-m-tolyl)(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]-o-toluidine monohydrochloride CI 42520     Violet  Rinse-off products  5 ppm  
68 Hydrogen [4-[[4-(diethylamino)phenyl][4-[ethyl[(3-sulphonatobenzyl)amino]-o-tolyl]methylene]-3-methylcyclohexa-2,5-dien-1-ylidene](ethyl)(3-sulphonatobenzyl)ammonium, sodium salt CI 42735     Blue  Not to be used in products applied on mucous membranes   
69 [4-[[4-Anilino-1-naphthyl][4-(dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride CI 44045     Blue  Not to be used in products applied on the mucous membranes   
70 Hydrogen [4-[4-(dimethylamino)-.alpha.-(2-hydroxy-3,6-disulphonato-1-naphthyl)benzylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium, monosodium salt CI 44090   221-409-2  Green     
71 Hydrogen 3,6-bis(diethylamino)-9-(2,4-disulphonatophenyl)xanthylium, sodium salt CI 45100     Red  Rinse-off products   
72 Hydrogen 9-(2-carboxylatophenyl)-3-(2-methylanilino)-6-(2-methyl-4-sulphoanilino)xanthylium, monosodium salt CI 45190     Violet  Rinse-off products   
73 Hydrogen 9-(2,4-disulphonatophenyl)-3,6-bis(ethylamino)-2,7-dimethylxanthylium, monosodium salt CI 45220     Red  Rinse-off products   
74 Disodium 2-(3-oxo-6-oxidoxanthen-9-yl)benzoate CI 45350     Yellow    6% 
75 4',5'-Dibromo-3',6'-dihydroxyspiro[isobenzofuran-1(3H),9'-[9H]xanthene]-3-one and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 45370     Orange     
76 Disodium 2-(2,4,5,7-tetrabromo-6-oxido-3-oxoxanthen-9-yl)benzoate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 45380     Red     
77 3',6'-Dihydroxy-4',5'-dinitrospiro[isobenzofuran-1(3H),9'-[9H]xanthene]-3-one CI 45396     Orange    1%, when used in lip products 
78 Dipotassium 3,6-dichloro-2-(2,4,5,7-tetrabromo-6-oxido-3-oxoxanthen-9-yl)benzoate CI 45405     Red  Not to be used in eye products   
79 3,4,5,6-Tetrachloro-2-(1,4,5,8-tetrabromo-6-hydroxy-3-oxoxanthen-9-yl)benzoic acid and its soluble barium, strontium and zirconium lakes, salts and pigments CI 45410     Red     
80 Disodium 2-(2,4,5,7-tetraiodo-6-oxido-3-oxoxanthen-9-yl)benzoate and its insoluble barium, strontium and zirconium lakes, salts and pigments CI 45430   240-474-8  Red     
81 1,3-Isobenzofurandione, reaction products with methylquinoline and quinoline CI 47000     Yellow  Not to be used in products applied on mucous membranes   
82 1H-Indene-1,3(2H)-dione, 2-(2-quinolinyl)-, sulfonated, sodium salts CI 47005   305-897-5   Yellow     
83 Hydrogen 9-[(3-methoxyphenyl)amino]-7-phenyl-5-(phenylamino)-4,10-disulphonatobenzo[a]phenazinium, sodium salt CI 50325     Violet  Rinse-off products   
84 Sulfonated nigrosine color CI 50420     Black  Not to be used in products applied on the mucous membranes   
85 8,18-Dichloro-5,15-diethyl-5,15-dihydrodiindolo[3,2-b:3',2'-m]triphenodioxazine CI 51319     Violet  Rinse-off products   
86 1,2-Dihydroxyanthraquinone CI 58000     Red     
87 Trisodium 8-hydroxypyrene-1,3,6-trisulphonate CI 59040     Green  Not to be used in products applied on the mucous membranes   
88 1-Anilino-4-hydroxyanthraquinone CI 60724     Violet  Rinse-off products   
89 1-Hydroxy-4-(p-toluidino)anthraquinone CI 60725     Violet     
90 Sodium 4-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anthryl)amino]toluene-3-sulphonate CI 60730     Violet  Not to be used in products applied on the mucous membranes   
91 1,4-bis(p-Tolylamino)anthraquinone CI 61565     Green     
92 Disodium 2,2'-(9,10-dioxoanthracene-1,4-diyldiimino)bis(5-methylsulphonate) CI 61570     Green     
93 Sodium 3,3'-(9,10-dioxoanthracene-1,4-diyldiimino)bis(2,4,6-trimethylbenzenesulphonate) CI 61585     Blue  Rinse-off products   
94 Sodium 1-amino-4-(cyclohexylamino)-9,10-dihydro-9,10-dioxoanthracene-2-sulphonate CI 62045     Blue  Rinse-off products   
95 6,15-Dihydroanthrazine-5,9,14,18-tetrone CI 69800     Blue     
96 7,16-Dichloro-6,15-dihydroanthrazine-5,9,14,18-tetrone CI 69825     Blue     
97 Bisbenzimidazo[2,1-b:2',1'-i]benzo[lmn][3,8]phenanthroline-8,17-dione CI 71105     Orange  Not to be used in products applied on mucous membranes   
98 2-(1,3-Dihydro-3-oxo-2H-indazol-2-ylidene)-1,2-dihydro-3H-indol-3-one CI 73000     Blue     
99 Disodium 5,5'-(2-(1,3-dihydro-3-oxo-2H-indazol-2-ylidene)-1,2-dihydro-3H-indol-3-one)disulphonate CI 73015   212-728-8  Blue     
100 6-Chloro-2-(6-chloro-4-methyl-3-oxobenzo[b]thien-2(3H)-ylidene)-4-methylbenzo[b]thiophene-3(2H)-one CI 73360     Red